Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

Visual SLAM in dynamic environments based on object detection

A great number of visual simultaneous localization and mapping (VSLAM) systems need to assume static features in the environment. However, moving objects can vastly impair the performance of a VSLAM system which relies on the static-world assumption. To cope with this challenging topic, a real-time and robust VSLAM system based on ORB-SLAM2 for dynamic environments was proposed. To reduce the influence of dynamic content, we incorporate the deep-learning-based object detection method in the visual odometry, then the dynamic object probability model is added to raise the efficiency of object detection deep neural network and enhance the real-time performance of our system. Experiment with both on the TUM and KITTI benchmark dataset, as well as in a real-world environment, the results clarify that our method can significantly reduce the tracking error or drift, enhance the robustness, accuracy and stability of the VSLAM system in dynamic scenes.     

带空气室脉冲水射流系统通用分析法

针对所提出的用空气室引发水力共振以增强脉冲水射流的设想,应用水力瞬变特征线解法,建立系统的数学模型,差分网格只取脉冲源、空气室和喷嘴3个边界点,采用变时步法解算。这种方法具有灵活性大、受限制小、便于使用的突出优点。     

多通道舰空导弹武器系统反导决策模型研究

当前水面舰艇面临着严重的反舰导弹威胁,特别是在饱和攻击的条件下,常规的单通道舰空导弹系统已经不能满足作战的需要。多通道舰空导弹武器系统具有同时引导多枚导弹拦截多批目标的能力,可以充分发挥系统的能力,相应的反导决策在防空作战中起到重要作用,反导决策的正确性和合理性直接影响防空作战效果。在对反导决策过程和制约因素进行分析的基础上,通过0-1决策模型,得到了舰空导弹武器反导的优化决策模型,较好地满足了使用多通道舰空导弹系统对多目标打击决策的合理性和有效性。     

大延时网络中的主动队列管理机制

研究了网络延时对路由器主动队列管理机制的影响,分析了几种典型主动队列管理算法在大延时网络中的性能。在介绍了基于内模补偿的DC-AQM算法的优缺点之后,根据PID控制器延时补偿的Ziegler-Nichols设定方法,提出了ZNDC(Ziegler-Nichols delay compensation)AQM算法并进行了仿真实验验证,实验结果表明算法达到了预期的目标。     

某型舰炮火控系统建模与仿真

简要介绍了某型舰炮火控仿真系统的训练、教学和和科研功能设计方案,硬件组成和必需的软件模块.在对一批空中目标拦截的战术设定情况下,给出了作战仿真流程图,列出了我舰及目标运动状态和姿态、噪声仿真、系统解命中、射击效果在线评估等数学模型.最后指出在建立数学模型时新的跟踪机制、解命中体制和滤波外推算法是三个技术难点,而在仿真过程中必须注意分布式、可视化和时钟统一等关键技术.     

舰艇武器布置问题的一种协同优化算法

针对舰艇武器布置问题的特点,提出了一种基于粒子群优化和分类器系统的协同优化算法,以粒子群优化进行优化计算,用分类器系统消除约束.计算实例表明,该算法能较好地实现优化计算,并能节省大量的计算时间.     

L波段掺铒光纤放大器增益钳制及提高特性研究

报道了一种新型980 nm激光二极管(LD)泵浦高增益的掺铒光纤放大器(EDFA).通过加入中心波长为1 550 nm光纤光栅(FBG)可以明显提高增益,并分析了增益钳制的原理.实验得到其增益比无FBG结构EDFA提高8 dB,并得到了小信号输入时增益25 dB的有效钳制.     

基于固有时间尺度分解的能量算子解调法及故障诊断应用

针对Teager能量算子包络解调方法主要用于对单分量的调幅调频信号进行解调,而真实机械故障信号多为多分量的调幅调频信号的问题,提出了能量算子与固有时间尺度分解相结合的解调方法.首先,利用固有时间尺度分解法将原始振动信号分解为若干个固有旋转分量和一个单调趋势项,并基于波形匹配算法实现原始数据的自适应端点延拓以解决分解过程中的端点效应;然后再选取合适的固有旋转分量,利用能量算子方法实现调制信号的包络解调;最后,将该方法应用于仿真信号和故障模拟信号.结果表明:该方法能有效地提取机械振动信号的故障特征.     

两个积分中值定理内点性的新证明

积分第一中值定理和第二中值定理是定积分理论中两个十分重要的定理,近年来关于其内点性的讨论非常广泛。首先根据连续函数的介值定理,用一种新方法证明积分第一中值定理的内点性;然后提出一个实例,说明积分第二中值定理在通常条件下不具有内点性;最后利用定积分存在的充要条件和Abel变换的手段,证明积分第二中值定理在加上一个非常一般化的条件时具有内点性。